CHAP. 26.—VERDIGRIS; EIGHTEEN REMEDIES.
Verdigris[1] is also applied to many purposes, and is prepared
in numerous ways. Sometimes it is detached already formed,
from the mineral from which copper is smelted: and sometimes
it is made by piercing holes in white copper, and suspending
it over strong vinegar in casks, which are closed with
covers; it being much superior if scales of copper are used for
the purpose. Some persons plunge vessels themselves, made
of white copper, into earthen pots filled with vinegar, and
scrape them at the end of ten days. Others, again, cover the
vessels with husks of grapes,[2] and scrape them in the same
way, at the end of ten days. Others sprinkle vinegar upon
copper filings, and stir them frequently with a spatula in the
course of the day, until they are completely dissolved. Others
prefer triturating these filings with vinegar in a brazen
mortar: but the most expeditious method of all is to add to
the vinegar shavings of coronet copper.[3] Rhodian verdigris,
more particularly, is adulterated with pounded marble; some
persons use pumice-stone or gum.
The adulteration, however, which is the most difficult to
detect, is made with copperas;[4] the other sophistications
being detected by the crackling of the substance when bitten
with the teeth. The best mode of testing it is by using an
iron fire-shovel; for when thus subjected to the fire, if pure,
the verdigris retains its colour, but if mixed with copperas, it
becomes red. The fraud may also be detected by using a leaf
of papyrus, which has been steeped in an infusion of nut-galls;
for it becomes black immediately upon the genuine verdigris
being applied. It may also be detected by the eye; the green
colour being unpleasant to the sight. But whether it is pure
or adulterated, the best method is first to wash and dry it, and
then to burn it in a new earthen vessel, turning it over until
it is reduced to an ash;[5] after which it is pounded and put by
for use. Some persons calcine it in raw earthen vessels, until
the earthenware becomes thoroughly baked: others again add
to it male frankincense.[6] Verdigris is washed, too, in the same
manner as cadmia.
It affords a most useful ingredient for eye-salves, and from
its mordent action is highly beneficial for watery humours of
the eyes. It is necessary, however, to wash the part with
warm water, applied with a fine sponge, until its mordency
is no longer felt.
1. "Ærugo." The researches of modern chemists have ascertained the
composition of verdigris to be a diacetete of copper; the sesquibasic
acetate and the triacetate are also to be considered as varieties of this
substance; we have an exact analysis of these salts in the "Elements" of
the late Dr. Turner, the Sixth Edition, edited by Professor Liebig and Mr.
W. Turner, pp. 931, 2. Most of the processes described in this Chapter
are mentioned by Dioscorides.—B. See also Beckmann, Hist. Inv. Vol. I.
p. 171, et seq., Bohn's Edition.
2. According to Brotero, this is the process generally adopted in France,
in preference to the employment of vinegar in a pure state.—B.
3. The form of copper which was termed "coronarium" has been already
described in Chapter 22.—B.
4. "Atramento sutorio." "Shoemakers' black." See Chapters 27 and
32 of this Book.
5. Until it assumes an ashy colour, Dioscorides says.—B.
6. See B. xii. cc. 30, 32.